Bis{μ-2-[(N,N-diisopropylcarbamothioyl)sulfanyl]acetato-κ2 O:O′}bis(bis(4-chlorobenzyl){2-[(N,N-diisopropylcarbamothioyl)sulfanyl]acetato-κ2 O,O′}tin(IV))
نویسندگان
چکیده
The dinuclear title complex, [Sn(2)(C(7)H(6)Cl)(4)(C(9)H(16)NO(2)S(2))(4)], lies on a center of inversion. The Sn(IV) atoms are chelated by one of the two carboxyl-ate ions; the other carboxyl-ate ion bridges two metal atoms. The geometry of the six-coordinate Sn(IV) atom is a distorted trans-C(2)SnO(4) octa-hedron [C-Sn-C = 155.32 (8)°].
منابع مشابه
Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ2 O:O)bis[(acetato-κ2 O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ2 O,O′)lanthanum(III)]
The N-heterocycles in the centrosymmetric title compound, [La(2)(C(10)H(9)NO)(4)(CH(3)COO)(2)(NO(3))(4)], exist in the zwitterionic form. One heterocycle binds to a metal center whereas the other bridges two metal centers. Each La atom is chelated by an acetate and two nitrate groups and is surrounded by nine O atoms in a distorted tricapped trigonal-prismatic coordination environment. The N-H ...
متن کاملTetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ4 O:O′;κ3 O,O′:O;κ3 O:O,O′-bis{[2-(3,4-dimethoxyphenyl)acetato-κ2 O,O′](1,10-phenanthroline-κ2 N,N′)samarium(III)}
In the centrosymmetric dinuclear title complex, [Sm(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the Sm(III) ion is nine-coordinated by seven O atoms of five 2-(3,4-dimeth-oxy-phen-yl)acetate (DMPA) ligands and two N atoms of one bis-chelating 1,10-phenanthroline (phen) ligand, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordinate in bis-chelate, bridging and br...
متن کاملTetra-μ-acetato-κ4 O:O′;κ3 O,O′:O;κ3 O:O,O′-bis[(acetato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)europium(III)]
In the title centrosymmetric dinuclear complex, [Eu(2)(CH(3)CO(2))(6)(C(12)H(8)N(2))(2)], the Eu(III) atom is nine-coordinated by two N atoms from a 1,10-phenanthroline ligand and seven O atoms from five acetate ligands (two bidentate, three monodentate). The crystal structure is stabilized by π-π stacking inter-actions between the pyridine and benzene rings of adjacent mol-ecules, with a centr...
متن کاملTetra-μ-acetato-κ4 O:O′;κ3 O,O′:O′;κ3 O:O,O′-bis[(acetato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)europium(III)]
In the title centrosymmetric dinuclear Eu(III) complex, [Eu(2)(CH(3)COO)(6)(C(12)H(8)N(2))(2)], each Eu(III) cation is coordinated by seven O atoms from five acetate anions and two N atoms from one phenanthroline ligand in a distorted tricapped trigonal-prismatic geometry. Four acetate anions bridge two Eu(III) cations to form the dinuclear complex, with an Eu⋯Eu distance of 3.9409 (8) Å. Weak ...
متن کاملDi-μ-acetato-κ3 O,O′:O;κ3 O:O,O′-bis[(acetato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)cadmium(II)]
The title compound, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(8)N(2))(2)], consists of dimeric units built up around a crystallographic symmetry centre. Each cadmium(II) unit is chelated by a 1,10-phenanthroline (phen) group and two acetate ligands, one of which also acts as a bridge, linking both seven-coordinated cadmium(II) centres. The crystal structure is governed by a single π-π inter-action between...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011